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Explainer: Are 'self-disinfecting' coatings, the latest COVID-19 hero, too good to be true?

WONG PEI TING • April 19, 2020
The disinfecting coating agent called SDST being applied to lift buttons at public housing blocks.

Published 19 APRIL, 2020 UPDATED 19 APRIL, 2020

SINGAPORE — Masks and hand sanitiser aside, demand for “self-disinfecting” coatings that are said to be able to kill germs and viruses, including the coronavirus that causes Covid-19, has skyrocketed lately.


But do the latest heroes on the scene really live up to expectations, or have they already buckled under the abuses of many fingers weeks into their application on lift buttons at public housing estates, Changi Airport facilities and ATM machines alike?


TODAY spoke to experts to understand the science behind the technology and found that its efficacy could become compromised weeks into its application, even though the protective coating was advertised to be able to self-disinfect surfaces for up to three months or more a spritz.


Indeed, an interested party – Mr Jerry Lim, managing director of furniture supplier Alma Contract Singapore who recently ventured into the sanitising business – conducted swab tests to see if the claims held up, and found unsatisfactory results.


An adenosine triphosphate (ATP) test on a button in a lift connecting the arrival and departure halls at Changi Airport Terminal 2 on April 4 yielded a reading of 1,215 relative light units (RLU) – a high microbial count.


The readings are much lower on surfaces at the terminal such as a railing beside its Starbucks outlet (72) and a touch-screen surface of a self-check-in kiosk (84).


The industry takes values under 100 to be clearly associated with clean surfaces.

Earlier this week, his team also tested lift buttons at two public housing estates and found the RLU readings on those surfaces to be in the 500 to 600 range. Tests they conducted on treated ATM machines yielded readings in the 300s.


FIRST UP, WHAT’S THE HYPE?

SDST is one brand of coating that received media attention lately after Changi Airport Group’s charity arm, Changi Foundation, donated 650 litres of the product for use at 26,000 lifts across all Housing and Development Board (HDB) estates here.


Microbiologist Yeo Wee Ming, managing director of SUTL EnvironTech which distributes it, claimed that it can remain effective for up to 90 days without reapplication, even with repeated scrubbing.


Dr Mary Chan Bee Eng, a professor at the School of Chemical and Biomedical Engineering at Nanyang Technological University, said this can happen because anti-microbial coatings involve compounds that can poke “holes” on the membranes of microbes to reduce their ability to infect.


Usually, these microbe-killing compounds – already found in many general household products – can easily be washed away from the surfaces they are applied on.


SDST, for instance, contains benzalkonium chloride, which is the active ingredient in certain Dettol, Clorox, Cif, Magiclean and Mr Muscle products that is said to be effective against the coronavirus.


What makes the coating different is that scientists had found a way to anchor such compounds onto surfaces using silane chemistry, a compound that promotes adhesion between dissimilar materials.


It leaves an invisible residual film that can still continue to do its disinfecting work for days even after drying.


WHY DOESN’T IT SEEM TO WORK IN REAL LIFE?


While these products are effective, Assistant Professor Lim Kaiyang who lectures at the Singapore Institute of Technology said their effective periods are “often difficult to determine”.


They depend on the concentration of microbes it had been exposed to, and its environmental conditions, such as whether it was exposed to “rough treatment”, he pointed out.


“Once the coating is overwhelmed, it eventually loses its anti-microbial activity and becomes ineffective,” Dr Lim said. “From then on, the treated surface is once again open to contamination by microbes.”


He used the analogy of a coat of paint on the wall to illustrate how the anti-microbial coat can last for years if left untouched, but will come off if it is scratched every now and then.


Dr Chan said it is possible that the self-disinfecting surfaces become contaminated with use as the efficacy of coatings depends on the following factors:


  • The adhesion quality of the coating to the applied surface
  • The amount of virus and bacteria deposited on it
  • Force asserted on the coated surface during cleaning
  • Surface acidity
  • Dirt deposited


Notably, “the surface can become covered with ‘killed’ viruses and bacteria so that they cannot kill ‘fresh’ viruses and bacteria again”, she said.


SO, HOW EFFECTIVE IS IT REALLY?


Speaking to TODAY, scientist Steve Kritzler, who is behind anti-microbial coating products Aeris Active and Evocide Extra, would only claim that their residual film, when used in high traffic areas, can remain active for seven days, or 200 hand touches.


“In low traffic areas, we have certainly validated periods of over 90 days… (But) frankly, in any high traffic area, re-application of the product more regularly than 90 days is (required),” said the technical director at the Australia-based Novapharm Research.


Dr Kritzler added that there is currently no anti-microbial coating that can effectively control microbial populations for long periods.


The only surface that managed to achieve this against bacteria and fungi is a “very expensive” material called anti-microbial copper, he said.


Over a video interview on Saturday (April 18), Dr Yeo said coating technologies infusing silane chemistry had been around for more than 20 years, but it alone can only give 30 days of protection or less, depending on abrasion and frequency of the surface’s use.


He said the SDST product included a few proprietary molecules that work together with the silane quaternary ammonia compounds to give an extended period of protection of up to 90 days.


Responding to claims of high ATP counts found on surfaces treated by SDST, Dr Yeo said the high readings require further investigation.


Asked what could have gone wrong, he said that it could be because the coating had been scratched off. He observed at least four users hitting the buttons with their keys on Friday alone when he returned to some HDB lifts a month after SDST had been applied.


Another reason could be that certain hand sanitiser or hand cream smeared onto the surfaces had thrown off the ATP readings, Dr Yeo said. To demonstrate, he squirted drops of two brands of hand sanitiser on a surface in his room and conducted ATP tests there. The two readings are 9,248 RLU and 3,343 RLU.


High readings do not always mean that the coating had lost its efficacy way before the 90-day mark, he added.


WHAT SHOULD PEOPLE'S ATTITUDES BE THEN?


While he is selling the product, Dr Yeo said it would be “harmful and misleading” for the community to think that they no longer need to wash their hands since such coatings had been used to treat frequently-touched surfaces in public.


The coatings merely reduce the risk of transmission, he said.


Dr Yeo reiterated that the product is self-disinfecting but not “self-cleaning”, since dirt, oil or saliva can still cover the coatings, rendering its properties ineffective.


Dr Lim said the general public should still adopt a “conservative approach” when implementing such products to protect against virus transmission and “not be over-reliant on them”.


“Always know that there are limitations in terms of how effective and sustainable such coatings can be,” he added.


“While such coating, when effective, can act as a hurdle against contaminations, it is still advisable for us to have good hygiene practices to minimise the chance of getting microbial or virus contaminations, or both.”


By Decon7 Team 04 Dec, 2020
There has been a longtime mystery for the so called “invisible barrier” left behind resisting microbial growth on surfaces treated with Decon7. These surfaces or substrates include but not limited to the following; Carpet, clothing, brick, vinyl (fences, siding, curtains – poultry barns), cement, stucco, all wood for construction, HVAC ducting, evaporator coil pans, sheetrock, filter material, etc. Unlocking the mystery has been quite puzzling and from recent lab testing done some discoveries have taken place to explain this chemical reaction; Firstly the Part I formulation has an extensive ingredient list (proprietary), and there is one ingredient that has decomposition properties. Secondly the Part II is mainly H2O2 – 7.9% Hydrogen Peroxide which has penetration and oxidation properties. When the 2 parts come together they create a completely different action than if they were applied separately. Part I has decomposition capabilities within the main ingredients, this decomposition action begins to take place from the Part II joining. The reactivity and “dwell” time of the 2 formulations mixed eventually breaks each formulation down to the so called “barrier”. During this “dwell” time the 2 parts are capable of penetrating spore walls and destroying the mycotoxins or cytotoxins within the spore. Because of this it becomes extremely effective when used in a fog application. The fog or mist is atomized to a small enough micron to hang in an air space long enough to degrade and destroy any airborne spore or surface mold spore or colony. The so called “barrier” is the resulting chemical reaction of the 2 components degrading each other to the point of making a “hardened” surface, mostly of an Alkali and peroxycarbonate. A portion of the alkali (carbonate) rearranges in such a manner to form a water insoluble compound. This compound “barrier” creates an alkaline surface with a pH high enough - (pH of over 8), to deter and inhibit growth of microorganisms. This resulting barrier would also be able to be classified as a “green” final composition given the decomposition of most initial ingredients. And the so called “residue” left behind would be classified as a mined substance. The benefit of such an “invisible barrier” would be the fact that it would be completely non-toxic, extremely resistant to microorganism growth, mold and algae. The real benefit is while the 2 parts are active (8 to 12 hours) it becomes deadly to any spore, bacteria, virus or microorganism. And having this product also capable of creating a “zone of inhibition” it really becomes a standalone 2 part formulation unlike anything on the market. Treating substrates such as sheetrock paper, plastics, vinyl, or even air filtration material become reality, and now to claim not necessarily killing microorganisms, but creating a barrier that is resistant for any growth and is water insoluble is quite remarkable. Decontamination and cleaning test sites on roofs, decks, siding, (vinyl & stucco) have been ongoing for up to 4 years. Also remodel projects with moisture intrusions creating mold issues have been conducted. There has been no recorded re growth of any mold or algae on any surfaces treated with the Decon7 formulations. Mold remediation in homes and commercial properties using Decon7 is in the hundreds of thousands of square footage treated by the fogging and spraying method. Industrial Hygienists have been engaged for testing spore activity before and after, resulting tests have indicated the non-viable spore counts to be near zero on most sites. The residue is nontoxic, nonflammable and completely environmentally safe. With comparisons being made daily to all other products on the market – there has not been one that can claim these safety standards and perform even close to our Decon7 line of products. 長期以來,人們一直對所謂的“看不見的屏障”感到困惑,因為3D處理的表面上屏障微生物無法抵抗及生長。 這些表面包括但不限於以下; 地毯,衣服,磚,乙烯樹脂(柵欄,壁板,窗簾-家禽舍),水泥,灰泥,所有建築用木材,HVAC管道,蒸發器盤,薄板岩,過濾材料等。 最近的實驗室測試做了一些發現,可以解釋這種化學反應。 首先,Part1具有豐富的成份具有分解獨特性。 其次,Part2主要是H2O2-7.9%的過氧化氫,具有滲透和氧化性能。 當兩個部分放在一起時,它們將產生與單獨應用時完全不同的動作。 Part1在主要成分內具有分解能力,這種分解作用從Part1的加入開始發生。 混合的兩種製劑的反應性和“停留”時間最終使每種製劑分解成所謂的“屏障”。 在此“停留”時間內,這兩個部分能夠穿透孢子壁並破壞孢子內的真菌毒素或細胞毒素。 因此,當用於霧化應用時,它變得極為有效。 霧或霧被霧化到足夠小的微米程度,以在空氣空間中懸掛足夠長的時間,以降解並破壞任何空氣傳播的孢子或表面黴菌孢子或菌落。 所謂的“屏障”是兩種組分相互降解到最終形成“硬化”表面的化學反應,主要是鹼和過氧碳酸鹽。 這種化合物“屏障”可形成鹼性表面,其pH值足夠高(pH值超過8),可以阻止和抑制微生物的生長。 考慮到大多數初始成分的分解,由此產生的屏障也可以歸類為“綠色”最終組成。 留下的所謂“殘渣”將被歸類為礦物質。這種“隱形屏障”的好處是它完全無毒,對微生物的生長,黴菌和藻類具有極強的抵抗力。 真正的好處是,當這兩個部分都處於活動狀態(8到12小時)時,它對任何孢子,細菌,病毒或微生物都具有致命性。 而且,由於該產品還能夠產生“抑制區域”,因此它實際上成為了獨立的兩部分配方,與市場上的任何產品都不一樣。 處理諸如薄岩紙,塑料,乙烯基或什至是空氣過濾材料之類的基質已成為現實,現在聲稱不必殺死微生物,但創造出一種對任何生長都具有抵抗力且不溶於水的屏障,這是非常顯著的。 屋頂,甲板,壁板(乙烯基和灰泥)的去污和清潔測試場地已經進行了長達4年。 還進行了帶有潮氣侵入而導致發霉的重塑項目。 在用3D配方處理過的任何表面上,沒有任何黴菌或藻類再生的記錄。 使用3D對房屋和商業物業中的黴菌進行修復的方法,是通過霧化和噴塗方法處理的數十萬平方英尺。 工業衛生學家之前和之後都參與了孢子活性測試,結果表明大多數地方的無效孢子數都接近於零。 殘留物無毒,不易燃且完全環保。 每天都與市場上的所有其他產品進行比較-尚無一種產品可以聲稱有這些安全標準,甚至可以接近3D這類產品。
By Decon7 Team 13 Oct, 2020
Decon7 has been working hard to expand production in response to increased global demand for disinfectants due to the coronavirus pandemic. In addition to adding six new production facilities, we have also become kosher- and Halal-certified, allowing us to distribute products in even more countries.
By Decon7 Team 06 Oct, 2020
The global pandemic has caused disinfectant manufacturers to scramble to get EPA-approved label claims, and it’s not surprising that many companies have seen a dramatic increase in production. Manufacturing of D7 is no exception. Before the pandemic, D7 was produced in two facilities. Because demand has increased significantly, it is now made in eight different locations. 
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